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Star Trek: Enterprise Season 1 Episode 15
Archer and the crew are disappointed to discover that T’Pol has been ordered by the Vulcan High Command to leave Enterprise–and equally frustrated at her seeming indifference to leaving their ranks. T’Pol’s last mission as a Starfleet officer, however, proves eventful when she and Archer are kidnapped by a militant faction on an alien planet.
Season 1 - Sep. 26, 2001
Season 2 - Sep. 06, 2003
Season 3 - Nov. 28, 2004
Season 4 - Oct. 08, 2004